What Radioactivity Is
Radioactivity was discovered in 1896 by A. H. Becquerel, who found that uranium salts emitted a penetrating radiation able to fog a photographic plate even through black paper and a silver sheet. Subsequent experiments established that the effect was a nuclear phenomenon: an unstable nucleus undergoes a spontaneous transformation called radioactive decay. Marie and Pierre Curie extended the work by isolating two far more active elements, radium and polonium, from uranium ore.
In 1899 Rutherford analysed the Becquerel rays and identified two distinct components, the alpha particles and the beta rays; the third component, gamma rays, was later established by P. Villard. The defining feature of the process is that it is spontaneous — the decay rate is independent of external factors such as temperature and pressure — and that in alpha or beta emission a nucleus of one element is converted into a nucleus of a new element.
Heavier nuclei face an intense electrostatic repulsion among their protons. Neutrons act as the binding "glue", but beyond a point even extra neutrons cannot keep such nuclei stable. To reach a more stable configuration the nucleus disintegrates, emitting alpha and beta particles along with gamma rays.
Radioactivity is the phenomenon in which nuclei of a given species transform by giving out α, β or γ rays. Alpha rays are helium nuclei, beta rays are electrons (or positrons), and gamma rays are electromagnetic radiation of wavelengths shorter than X-rays.
The Three Decay Modes
Three types of radioactive decay occur in nature. In alpha decay a helium nucleus $^{4}_{2}\mathrm{He}$ is emitted. In beta decay, electrons or positrons — particles with the same mass as the electron but opposite charge — are emitted. In gamma decay, high-energy photons (hundreds of keV or more) are emitted. In every nuclear disintegration both the charge number $Z$ and the mass number $A$ are conserved, and this single rule is what lets us predict the daughter nucleus.
| Decay | Emitted particle | Change in A | Change in Z | Penetrating power |
|---|---|---|---|---|
| Alpha | Helium nucleus ⁴₂He |
−4 | −2 | Lowest — stopped by 0.02 mm Al |
| Beta-minus (β⁻) | Electron e⁻ + antineutrino |
0 | +1 | ~100× alpha; few mm of Al |
| Beta-plus (β⁺) | Positron e⁺ + neutrino |
0 | −1 | Similar to β⁻ |
| Gamma | High-energy photon γ |
0 | 0 | Highest — several cm of iron/lead |
Alpha Decay
In alpha decay the nucleus emits an alpha particle, which is a helium nucleus $^{4}_{2}\mathrm{He}$ made of two protons and two neutrons. Because two protons and two neutrons leave together, the parent's mass number drops by 4 and its atomic number drops by 2. The general transformation is written
$$^{A}_{Z}X \;\longrightarrow\; ^{A-4}_{Z-2}Y \;+\; ^{4}_{2}\mathrm{He}$$
The daughter $Y$ is a new element two places lower in the periodic table. Alpha particles are charged, so they deflect in electric and magnetic fields. They have a very high ionizing power — a single alpha particle can ionize thousands of gas atoms before it is absorbed — but a correspondingly low penetrating power, being stopped by an aluminium sheet about 0.02 mm thick. The energies of the emitted alpha particles are characteristic of the emitting nucleus.
Uranium $^{238}_{92}\mathrm{U}$ undergoes alpha decay. Identify the daughter nucleus.
Mass number: $238 - 4 = 234$. Atomic number: $92 - 2 = 90$, which is thorium. The product is $^{234}_{90}\mathrm{Th}$, conserving both $A$ and $Z$ across the equation $^{238}_{92}\mathrm{U} \to {}^{234}_{90}\mathrm{Th} + {}^{4}_{2}\mathrm{He}$.
Beta Decay (β⁻ and β⁺)
Beta particles originate in the nucleus through the conversion of a neutron into a proton, or a proton into a neutron. There are two varieties. In beta-minus (β⁻) decay, a neutron becomes a proton, emitting an electron and an antineutrino:
$$n \;\longrightarrow\; p + e^{-} + \bar{\nu}, \qquad ^{A}_{Z}X \;\longrightarrow\; ^{\;\;A}_{Z+1}Y + e^{-} + \bar{\nu}$$
Since one neutron has turned into one proton, the atomic number rises by 1 while the mass number is unchanged. The same conversion happens to a free neutron, which is unstable and decays into a proton, an electron and an antineutrino with a mean life of about 1000 s; inside a stable nucleus, however, the neutron does not decay.
In beta-plus (β⁺) decay, a proton becomes a neutron, emitting a positron and a neutrino:
$$p \;\longrightarrow\; n + e^{+} + \nu, \qquad ^{A}_{Z}X \;\longrightarrow\; ^{\;\;A}_{Z-1}Y + e^{+} + \nu$$
Here the atomic number falls by 1 and the mass number again stays the same. The positron is the antiparticle of the electron: identical in mass, equal and opposite in charge. When a positron meets an electron the pair annihilates, releasing energy as gamma-ray photons. Beta particles deflect in electric and magnetic fields, ionize gas atoms far less strongly than alpha particles, and are roughly 100 times more penetrating, passing through a few millimetres of aluminium.
Mixing up the displacement rules — and forgetting the antineutrino
The most common error in displacement-law questions is misremembering how $Z$ shifts. Fix the four rules in this order: α gives $A-4$, $Z-2$; β⁻ keeps $A$ the same and pushes $Z+1$; β⁺ keeps $A$ the same and pushes $Z-1$; γ changes neither $A$ nor $Z$. A second trap is leaving out the (anti)neutrino — β⁻ emits an antineutrino ($\bar{\nu}$) and β⁺ emits a neutrino ($\nu$). When you balance a decay equation, balance only $A$ and $Z$; the neutrino carries no charge and effectively no mass number.
α: $A{-}4$, $Z{-}2$ · β⁻: same $A$, $Z{+}1$ · β⁺: same $A$, $Z{-}1$ · γ: no change in $A$ or $Z$.
Once you can name the daughter nucleus, the next step is timing the decay. See Radioactive Decay & Half-Life for the decay law, decay constant and half-life.
Gamma Decay
After an alpha or beta emission, the daughter nucleus is frequently left in an excited state, marked with an asterisk. It returns to a lower-energy state by releasing the surplus energy as a high-frequency electromagnetic photon — a gamma ray:
$$(^{A}_{Z}X)^{*} \;\longrightarrow\; ^{A}_{Z}X \;+\; \gamma$$
Because only the energy state changes and not the composition, gamma emission leaves both $A$ and $Z$ unchanged — no new element is formed. Gamma rays are not deflected by electric or magnetic fields, travel at the speed of light, and have the greatest penetrating power of the three, passing through several centimetres of iron and lead. Their ionizing power, by contrast, is the smallest. High-energy ("hard") gamma rays are used in the radiotherapy of malignant cells.
The Q-value of a Decay
The energy released in a nuclear process is its Q-value, defined as the final kinetic energy minus the initial kinetic energy. By conservation of mass–energy this can equally be written in terms of masses:
$$Q = \big(\text{sum of initial masses} - \text{sum of final masses}\big)c^{2}$$
A spontaneous decay requires $Q > 0$, meaning the combined mass of the products is less than the mass of the parent; the missing mass appears as the kinetic energy of the products and any emitted photon. If $Q$ were negative the decay could not occur on its own. This is why radioactivity always moves a nucleus toward a more tightly bound, lower-mass configuration.
Penetrating and Ionizing Power
The three radiations differ sharply in how far they travel and how strongly they ionize matter. Alpha particles are the most strongly ionizing but the least penetrating; gamma rays are the opposite, deeply penetrating but weakly ionizing; beta particles sit in between on both counts. This inverse relationship is a frequent qualitative-question target.
Displacement-law Practice
The displacement law is simply conservation of $A$ and $Z$ applied repeatedly along a decay sequence. To track a chain, apply the per-step rules in turn and balance the totals at the end. The worked example below mirrors the structure of the NEET 2024 chain question.
A nucleus $^{A}_{Z}X$ undergoes the sequence: α, then β⁺, then β⁻, then β⁻. By how much do $A$ and $Z$ change in total?
Track each step. α: $A-4$, $Z-2$. β⁺: $A$ unchanged, $Z-1$. β⁻: $A$ unchanged, $Z+1$. β⁻: $A$ unchanged, $Z+1$. Net change in mass number: $-4$. Net change in atomic number: $-2-1+1+1 = -1$. So the final product has mass number $A-4$ and atomic number $Z-1$.
Radioactivity — Alpha, Beta, and Gamma Decay
- Radioactivity is the spontaneous decay of an unstable nucleus into a more stable one, emitting α, β or γ radiation; both $A$ and $Z$ are always conserved.
- Alpha: emits $^{4}_{2}\mathrm{He}$; $A \to A-4$, $Z \to Z-2$. Highest ionizing, lowest penetrating power.
- Beta-minus: $n \to p + e^{-} + \bar{\nu}$; $A$ unchanged, $Z \to Z+1$. Beta-plus: $p \to n + e^{+} + \nu$; $A$ unchanged, $Z \to Z-1$.
- Gamma: excited nucleus emits a photon; no change in $A$ or $Z$. Highest penetrating, lowest ionizing power.
- The Q-value is $(\Sigma m_\text{initial} - \Sigma m_\text{final})c^2$; a decay is spontaneous only when $Q > 0$.